Hi James,
As it says on the front panel of the 2430, the max input voltage is 400 V, if you connect a signal with 500 Vdc you risk damaging the instrument.
Page 1-6 of the manual reinforces this and specifically says this is also true for AC coupled mode.
The trigger LF Reject mode only applies to the trigger path, it does not affect the channel acquisition path.
So, the 2430 does have an AC coupling mode, but your DC offset is so high that you risk damaging the instrument if you use it directly. Instead, you should use an external DC block (which is just a capacitor in series) rated for 500 Vdc before the channel input.